Friday, July 3, 2015

LEGO STEM women


I admit I am a little late to the table (lab table?) only just discovering the August 2014 LEGO Research Institute and its women scientists: astronomer, chemist, and paleontologist. I heard about it a couple weeks ago, possibly through the #distractinglysexy Twitter feed in response to Nobel Laureate Sir Tim Hunt’s comments about “girl” scientists crying in the lab and making male lab workers fall in love with them (http://www.bbc.com/news/blogs-trending-33099289; http://www.ucl.ac.uk/news/news-articles/0615/100615-tim-hunt).

LEGO Research Institute

Coincidently, right after receiving the Research Institute last week through Amazon (sold out through LEGO), I was going through a pile (big pile) of unread Eos newspapers, the weekly, now biweekly and online (Eos.org), newspaper of the American Geophysical Union (agu.org), and found a September 2014 article about the Dutch geoscientist, Ellen Kooijman, who designed the Research Institute set (https://eos.org/articles/lego-set-features-women-scientists). Kooijman and others had observed that few female LEGO people came in adventure or career settings. Scientific American had a blog post just two weeks ago about the evolution of STEM professional LEGO women since the first minifigure in 2013 (http://blogs.scientificamerican.com/voices/lego-adds-more-women-in-science-to-its-lineup/).

Designing LEGO sets in her spare time under the pseudonym, Alatariel, Kooijman works through LEGO Ideas (https://ideas.lego.com/), a LEGO site for fans to propose new sets. If proposals gather 10,000 votes, they are reviewed by LEGO for possible production. Kooijman describes the evolution of the Research Institute also in her blog post at http://alatarielatelier.blogspot.se/p/female-minifigure-set.html?zx=7fc735e0789785ac and an interview at http://jaysbrickblog.com/2014/09/14/interview-ellen-kooijman-designer-lego-research-institute/.

Kooijman’s next set to hit stores, on August 1, is the Big Bang Theory, based on the popular television show, and set in Sheldon and Leonard’s apartment (https://ideas.lego.com/projects/58456). “Science Adventures” (https://ideas.lego.com/projects/83039) is another proposed LEGO set by Kooijman that is in review, having reached 10,000 votes in less than two months. This set includes an archeologist, wildlife biologist with tiger, and a field geologist with outcrop, hammer, geologic map, and Brunton compass.

“Research geology” (https://ideas.lego.com/projects/93813) is a proposed set by another designer that still needs about 6600 votes to reach LEGO review. It has two vignettes 1) an outcrop with male and female geologists and a dog: “there's always the obligatory geology dog” (been there, done that, love that!), and 2) a microscope lab setting with SEM and light microscope (I can fantasize or play that the petrographic microscope is reflected light, like that used in organic petrology since one needs reflected light to also check polished SEM mounts).

Some STEM professionals, including women, appear in the LEGO Minifigure sets (http://blogs.scientificamerican.com/guest-blog/breaking-brick-stereotypes-lego-unveils-a-female-scientist/). I also bought another separate woman paleontologist minifigure (Collectible Minifigures Series 13) because she is wearing field gear, and, without her dinosaur bone and ammonite, can double as any field geologist before the “Science Adventures” set is released.  I used her for “scale” today in my #FridayFold tweet!


 Now to put together that Lego Research Institute dino skeleton. . .

Saturday, June 20, 2015

Coal and organic petrology bibliographic and information resources


            Back in 2002 at the annual AAPG (American Association of Petroleum Geologists) meeting in Houston, I hosted an exhibit booth for The Society for Organic Petrology (TSOP). It surprised me that not once, but at least twice, graduate students came up to me and said how much they appreciated the TSOP online bibliography of coal/organic petrology, geology, utilization articles. The students were from schools with limited organic petrology programs or library resources and found the TSOP bibliography invaluable.

            So, as we get into the summer when many graduate students or junior-senior undergraduate students may be concentrating on research rather than classes, here are some organic petrology resources.

Online bibliography:

TSOP reference page at http://tsop.org/references.html lists multiple topics: click on topics to download associated Microsoft Word documents (.docx). Last checked June 2024, many updated in 2021.

Online photomicrograph atlases:

US Geological Survey Organic Petrology Photomicrograph Atlas: http://energy.usgs.gov/Coal/OrganicPetrology/PhotomicrographAtlas.aspx (Lots of photos of macerals in coal and those in oil and gas shales.)

Crelling’s Petrographic Atlas of Coals and Carbons: http://www.coalandcarbonatlas.siu.edu/ (includes flyash and chars, cokes)

Indiana Geological Survey Atlas of Coal Macerals: http://igs.indiana.edu/Coal/Macerals.cfm

Books:

Available in various formats: Hardcover, paperback, or e-book. This list is not comprehensive, but include classics or my favorites.

Organic Petrology by Taylor, G.H., Teichmüller, M., Davis, A., Diessel, C.F.K., Littke, R., Robert, P., 1998: Gebrüder Borntraeger, Berlin, 704 pages. (This is the successor to Stach’s Textbook of Coal Petrology, 1982, 3rd ed., by Stach, E., Mackowsky, M.-Th., Teichmüller,  M., Taylor, G.H., Chandra, D., Teichmüller, R., Murchison, D.G., and Zierke, F., eds., Gebruder Borntraeger, Berlin, 535 p.)

Petroleum Formation and Occurrence (2nd. ed.) by B.P. Tissot and D.H. Welte, 1984, Springer Verlag, Berlin, 699 pages. Not organic petrology, but much on kerogen chemical evolution in the formation of petroleum.

Sedimentary organic matter by Richard V. Tyson, 1995, Chapman & Hall, London, 615 pages. Excellent comprehensive book on particulate organic matter with beautiful photos.

A Petrographic Atlas of Canadian Coal Macerals and Dispersed Organic Matter  by Judith Potter, Lavern Stasiuk, and Alexander Cameron (eds.) (http://www.cscop.org/atlas.php, available from Geological Survey of Canada, Calgary; now available on CD).

Coal-bearing Depositional Systems by Claus F. K. Diessel, 1992, Springer Verlag, 721 pages.

Coal Geology  by Larry Thomas, 2012 (2nd ed.), Wiley-Blackwell, 454 pages. This includes coal origin and petrology, but also exploration, mining, utilization, and environmental issues.

Applied Coal Petrology: The role of petrology in coal utilization by Isabel Suárez-Ruiz and John Crelling, 2008, Elsevier, 388 pages. Petrographic characterization for predicting behavior in various industrial processes like coke-making (steel industry), combustion, carbonization.

Professional scientific societies or society divisions whose activities concentrate on or include organic petrology (=petrography and geochemistry of coal and sedimentary organic matter including petroleum source rocks). TSOP, AAPG, GSA offer student research grant opportunities:

The Society for Organic Petrology (TSOP; www.tsop.org; besides the references page, there is a webpage with good links to other organic petrology-related sites: http://www.tsop.org/links/index.htm)

The International Committee on Coal and Organic Petrology (ICCP; www.iccop.org; this society is the governing organization for coal petrology terminology and organic petrographer accreditation)

The Canadian Society for Coal Science and Organic Petrology (http://www.cscop.org/)

Energy Geology Division, Geological Society of America (formerly the Coal Geology Division) (http://www.uky.edu/KGS/coal/GSA/; besides the general GSA student research grant programs, this division administers two specific research grants)

Energy Minerals Division (AAPG) (http://emd.aapg.org/; does include uranium)

Friday, June 19, 2015

The La Brea Tar Pits, with some igneous notes thrown in!


Two weeks ago my title was MOG: “Mother-of-the-Groom” in US wedding lingo. I was in Los Angeles, California, to celebrate the wedding of my son, whose apartment is just a couple blocks from the world-famous La Brea Tar Pits.


On the 1-mile walk from our hotel to son’s apartment, I cut through Hancock Park, which includes the campus of LACMA (Los Angeles County Museum of Art) and the Tar Pits. I walked under Levitated Mass, a large outdoor static-art piece (nod to any igneous geologists out there), opened to the public in 2012*, and then ESE through the grounds of the adjacent Tar Pits.
Levitated Mass in upper left corner, LACMA left and lower center, Tar Pits is green space. The large Lake Pit, with mammoth sculpture group, just to left of red pin; Project 23 boxes and exam space are little white dots in upper center (iPhone screen capture from Maps app).

Levitated Mass by Michael Heizer. Top photo from LACMA website; bottom photo, and all others with no attribution in this blog post, by Malinconico. The art piece includes the rock mass, walkway, and surrounding decomposed granite aggregate. The big rock is a diorite, probably Cretaceous, from Stone Valley Quarry, an aggregate quarry in the Jurupa Mountains near Glen Avon, California*.
Yes, people will tell you that the name, La Brea Tar Pits, is a redundancy since La Brea means “tar” in Spanish. Rancho La Brea was one of the original colonial Spanish land grants (http://www.tarpits.org/la-brea-tar-pits/timeline: History). Oil seeps upward from the Salt Lake oil field, in the northern part of the Los Angeles basin (http://www.searchanddiscovery.com/pdfz/documents/2012/20164gautier/ndx_gautier.pdf.html, slide 6; http://www.ucmp.berkeley.edu/quaternary/labrea.php), and the loss of volatile hydrocarbons leaves behind a tarry “gooey” residue AKA asphalt or bitumen.


Native Americans and later European settlers had used the tar for mortar, glue, caulking, medicine, and fuel. These uses were also known 5000 years ago in the Middle East (Daniel Yergin, The Prize, 1991, p. 23-24). The Hancock family, who owned Rancho La Brea in the late 19th/early 20th centuries, initially mined the asphalt, but later went into oil production on the land. Animal bones found in the La Brea tar were originally thought to be those of modern cattle, but, in 1875, it was recognized that the bones were actually fossils. Studies since have been “the core of late Pleistocene North American [paleontological] research”.
 
Excavating fossils 1913-15 at La Brea, Hancock Ranch, with oil wells in background (http://www.tarpits.org/la-brea-tar-pits/timeline: Excavations).
The present-day La Brea ponds filled with water and a scum of tar are remnants of former fossil (numbered on map) or mined-asphalt (Lake Pit) excavation pits (http://www.tarpits.org/visit/map). Besides these pits, a large number of tar-encased fossils are currently being “released” from Project 23: in 2006, during construction of an underground parking garage for LACMA, new fossil deposits were found. Twenty-three (therefore the name, Project 23) large wooden boxes were built around the masses of asphalt, to preserve the relationship of bones to each other, and removed, along with over 300 buckets of asphalt, for further examination. One can see remaining boxes outside on the grounds (photos below) with preliminary examination workstations and a blackboard describing the latest in what’s been found. Fossil exhibits, laboratories and research facilities are in the Page Museum onsite.
 
Pit 13
Tarry scum on surface of water in Lake Pit
Project 23 preliminary examination lab: Large wooden box, by blue wheelbarrow, is open, tent behind holds exam table space, other large boxes in background.
The fossils found at La Brea represent those from ~40,000 years ago (Late Pleistocene) into the Quaternary (<11,700 years ago). Quaternary fauna recovered are like those we live with today, but the Late Pleistocene fossils include large extinct mammals such as mastodons, mammoths, and the saber-toothed cats (http://www.tarpits.org/la-brea-tar-pits/timeline: Pleistocene). Most of the recovered fossils are those of predators and scavengers, assumably packs of predators chasing lone prey, all getting stuck in the tar (http://www.ucmp.berkeley.edu/quaternary/labrea.php). Several causes of the extinction at the end of the Pleistocene have been hypothesized. Climate change at the end of the last (Wisconsin) Ice Age, overkill by early man, or a combination of both are suggested. A very controversial hypothesis was climate change caused by impact or low-atmosphere explosion of a meteor over Canada (http://www.nature.com/news/evidence-found-for-planet-cooling-asteroid-1.13661 plus references for and against cited in linked PNAS paper and weblinks. I was never convinced of such an impact, and a 2023 open-access article in Earth-Science Reviews refutes that hypothesis.


I exited the Tar Pits by the large Lake Pit and its sculpture group of three Columbian mammoths: the mother tragically mired in tar, with panicked offspring and mate on the shore. The sorrowful scenario, although not fine art, is one of my three personal favorite emotive sculptures, the other two being The Dying Gaul  and The Peace Monument, with Grief leaning on the shoulder of History. 
Lake Pit with mammoth family and bubbling methane in foreground and to left behind mired mother. Page Museum is building in background
After the wedding, we drove to Las Vegas. On the north side of highway I-15 right before the California-Nevada state line are the Mountain Pass rare-earth-element (REE) mine and processing plant**. (At the time of this 2015 trip, Mountain Pass was owned by Molycorp, but the operation went bankrupt and was sold in 2017 [http://www.mining.com/mountain-pass-sells-20-5-million/]).The north rim of the open pit can be seen from the highway. The ore body is the Sulphide Queen stock, a 1.4 billion-year-old carbonatite (note a second igneous reference in this post!). Carbonatite is an igneous rock with a large percent of carbonate minerals (so not the organic carbon of this blog’s focus), which at Mountain Pass are primarily calcite, dolomite, and barite. The REE-bearing ore mineral is bastnäsite. Uses for REE include high-efficiency magnets in modern wind turbines and electric motors, and as coatings in compact fluorescent light bulbs, all important technologies in both saving energy and the transition to non-fossil fuel-based energy systems.

*Some Levitated Mass links about the sculpture, rock source and transport:
** Links to information on Mountain Pass REE deposit:
Mine and processing plant (when owned by Molycorp):
Geology:

Saturday, May 16, 2015

"The black blood of the machine age": Environmental impact of oil spills from ships sunk during the Battle of the Atlantic, offshore US, 1942


Last week, Friday, May 8, was the 70th anniversary of the end of World War II in Europe (Victory in Europe or VE day). The eastern US Atlantic States were spared direct attack, but offshore, shipping, primarily merchant shipping, was targeted heavily by German U-boats from January to August 1942. The quote in the blogpost title vividly refers to petroleum and comes from the documentary Victory at Sea (1952), Episode 3: "Sealing the Breach", which describes the German Atlantic submarine campaign in the first months following the United States’ entry into the war. The high US losses were due to ships traveling alone, nighttime glow from coastal cities silhouetting ship outlines, and lack of adequate Coast Guard and Navy ships and planes for defense against submarines. 

Once armed convoys were instituted for east coast shipping, losses decreased, but 350-400 ships had been sunk (sources vary on number). German U-boats then concentrated on shipping in the Gulf of Mexico (GoM) and the Caribbean. In the GoM, tankers carrying oil from Texas and Louisiana (Victory at Sea) and from refineries in Curacao and Aruba (MIT report cited below) were primary targets. Once armed convoys began there in late 1943, attacks also decreased.

My mother (born 1928) spent parts of many youthful summers in Point Pleasant Beach (PPB), New Jersey, an Atlantic coastal town with a great long white sand beach and boardwalk where her own mother's family had lived for generations. (PPB is about 18 miles from the former Naval Air Station at Lakehurst where the hydrogen-fueled German Zeppelin Hindenburg exploded and burned in May 1937: relatives remembered everyone standing outside to watch the Hindenberg fly over, then several minutes later hearing the fire sirens from many local communities. Blimps from Lakehurst did accompany WWII convoys along coastal New Jersey and New York: Sealing the Breach, minute 10:45.) My mother had mentioned that during World War II, oil and tar was seen on the beach from destroyed ships. Fifteen years later, we spent the entire 1957 summer living in PPB and made daily morning expeditions to the beach. I don't remember any tar balls, only occasional mass strandings of clear jelly fish at low tide, and continuing blimp surveillance  looking this time for Russian subs, but then I was only six. 

What was the immediate impact, and any lasting effects, of oil spills from tankers and ships torpedoed offshore New Jersey during WWII? I found an excellent 1977 report called Impact of Oil Spillage from World War II Tanker Sinkings by the Massachusetts Institute of Technology (MIT) Sea Grant Program. Motivated by then-recent tanker spills, such as the Argo Merchant, December 1976, the researchers focused on two US east coast locations: one main site, Cape Hatteras, North Carolina, because of the large number of nearby offshore sinkings, and one auxiliary site, Asbury Park, NJ, ten miles north of Point Pleasant Beach. The MIT team compiled data from historical records and archives, newspaper and magazine articles, and interviews with coastal residents and shipwreck survivors. They focused on tanker sinkings, which were 70% of US east coast attacks in 1942.

Here are volumes of oil from the report along with other spill volumes for comparison (Exxon Valdez, Argo Merchant, Torrey Canyon from Wikipedia; Deepwater Horizon, various sources including Federal reports; volumes originally given as metric tons or gallons were converted using http://www.cmegroup.com/tools-information/calc_crude.html):
  • US Atlantic coast sinkings, first half 1942: 3.55 million barrels (1/4 of this off Cape Hatteras)
  • Offshore central New Jersey, first half 1942, based on reported volumes of three torpedoed tankers: 264,000 barrels
  • Argo Merchant, tanker (1976): 183,333 barrels
  • Exxon Valdez, tanker (1989): 260,000 barrels spilled (commonly accepted number; was carrying 1.31 million barrels)
  • Torrey Canyon, tanker (UK; 1967): 762,000 barrels
  • Deepwater Horizon platform/well (2010): 4.9 million barrels 
The MIT researchers found there was little oil seen ashore in North Carolina north of Hatteras, but considerable amounts were on beaches to the south around Ocracoke Island, NC. However, there were no reliable reports of any severe or lasting damage to animal populations or habitats. The barrier islands of the North Carolina Outer Banks were true barriers protecting the rich fauna and flora of Pamlico Sound inside to the west. There were minor reports of oiled birds, but were no colloquial reports of offshore fish decreases; commercial fishery records were not available for 1940-45.

The second site examined by the MIT group was the Asbury Park, NJ, area. One of the reasons for this site choice was newspaper and magazine coverage of oil on the beaches, which were, and still are, a major tourist attraction and source of local income. The oil cleanup at Belmar, a beach town between Asbury Park and Point Pleasant Beach, was documented by a Life magazine photographer. The solution to clear oil from the beach surface sand was to fill long ten-foot-deep trenches, dug into the sand, with five feet of the oily sand before covering and burying with clean sand. There was concern that storms would exhume the oil, and variable reports on whether that happened. Like North Carolina, while oiled birds were reported, there was not any recognized effect on fish or bird population numbers.
Tar and oil from torpedoed US tankers on beach at Belmar, NJ, June 1942 
(all photos by Marie Hansen, Time-Life Picture Agency)


Oily sand at Belmar, NJ, June 1942


Ten-foot-deep trenches, on the beach, for burying oily sand at Belmar, NJ, June 1942


The MIT report concluded, that despite uncertainties due to limited data, “regional wildlife and economy survived with minimal difficulty”. The only remediation documented, besides the burning oil at time of attack, was the cosmetic New Jersey coastal beach clean-up.

That there was apparent minimal impact from WWII shipwrecked petroleum is surprising, compared to what we have more recently witnessed from the Deepwater Horizon spill. Major differences in those two events are, in my opinion:
1) Volume of released petroleum;
2) DwH leakage was continuous compared to more sporadic or intermittent torpedoing of ships;
3) Most of shipwreck leakage (point of entry into ocean) was assumably at or close to the surface, whereas, DwH was essentially all at the seafloor;

However, environmental threat from WWII shipwrecks is not past. (Reminder in reference to April 14 post on the Titanic: that ship only used coal, and Palmer and others’ 2003 report referenced there found little geochemical impact from coal on the seafloor.) In 2011, the Baltimore Sun reported that NOAA (National Oceanic and Atmospheric Administration) was "taking an inventory of more than 30,000 coastal shipwrecks — some of them casualties of the 1942 Battle of the Atlantic — and identifying those that pose the most significant threat". The subsequent report by the NOAA National Marine Sanctuaries office was completed in 2013 and submitted to the US Coast Guard. The assessment examined fuel type (oil, coal, wind/sail), salvage engineering and environmental risk assessment with historical and archeological data. The report concluded that 36 wrecks in US waters pose a "worst case discharge" threat from potential oil leakage, recommending 17 for further assessment. Seven of those are on the east coast from North Carolina to Massachusetts. Two more are off the east coast of Florida, five in the GoM, and the remaining three are along the US Pacific coast.

Some of the shipwrecks assessed may be eligible for the National Register of Historic Places, and many are gravesites. The most famous leaking WWII vessel is, of course, the USS Arizona sunk in Pearl Harbor, Hawaii, December 7, 1941. The rainbow oil sheen, the "black blood", always present is one somber reminder that the ship is also a tomb.

Tuesday, April 14, 2015

Titanic coal


            “A steady roar thundered across the water as everything moveable broke loose. There had never been a mixture like it-–29 boilers . . .the jeweled copy of the Rubaiyat . . . 800 cases of shelled walnuts . . . 15,000 bottles of ale and stout . . . huge anchor chains (each link weighed 175 pounds) . . . 30 cases of golf clubs and tennis rackets for Spalding . . . Eleanor Widener’s trousseau . . . tons of coal . . .”

            Walter Lord, A Night to Remember (1955)
Still from movie Titanic (1997)
(This blog has been updated slightly [links checked, new information], April 2018.)
       This April is the 103rd anniversary of the sinking of the Titanic. In 2007, I visited "Titanic: the Artifact Exhibition" at the Royal British Columbia Museum in Victoria, British Columbia, Canada, just before the start of that year’s combined meeting of The Society for Organic Petrology (TSOP) and the International Committee on Coal and Organic Petrology (ICCP). The museum is in the first block south of the majestic Empress Hotel on the inner harbor of Victoria. (I followed up my early Friday evening time-ticketed exhibit visit with supper and cocktail on the veranda of the Empress.) The Titanic, of course, is the great British steamship, touted as "unsinkable", that, on its maiden voyage from England to New York, struck an iceberg in the North Atlantic late on Sunday night, April 14, 1912; it sank beneath the ocean surface a few hours later in the early morning of April 15. The traveling exhibit, both through passenger and steamship effects recovered from the seafloor, and through recreations of the ship's interior, told the story of the disaster, life on board, the variety of passengers and their reasons for sailing. The exhibit exited at a gift shop; I purchased a pendant that enclosed a small piece of Titanic coal from the seafloor. I thought that was an appropriate remembrance for me, being 1) a coal petrologist, and 2) born on April 15.

        I had been aware that some of the coal from Titanic had been recovered and sold as part of the fundraising for Titanic recovery and research. Coal lumps, in fact, are the only recovered artifacts that have been ruled legal for sale since they are considered "natural" objects and not man-made (http://law.lclark.edu/live/files/11855-lcb163art8zekalapdf). Although some online photos or details on certificates of authenticity (COA) indicate that coal lumps could be very large (=>3 kg), one photo taken in a Titanic coal bunker before sailing shows mostly fist-size coal. Smaller pieces sold, including those in jewelry or crushed coal mounts, are taken from the larger pieces, and the COA for those specimens are, therefore, derivative. For example, the "object number" for the coal in my pendant is 94/0036: 1994 being the year of collection and 36 the sample number. An onboard photo of a crew member holding the supposed original 94/0036 coal nodule shows it to be about 30 cm x 25 cm x 10 cm. (This photo is no longer easy to find online but sometimes accompanies small pieces of coal for sale with the 94/0036 COA.) However, a Google image search for just "Titanic coal" produces several offered coal fragments, with COAs of different styles, but the same 94/0036 number! Certainly, many small pieces could be derived from the large original nodule, but is the volume sum of marketed pieces greater than the original whole? The seller at the above link does mention concern with authenticity of the coal being offered. (Addendum, June 11, 2015: Three days ago, I visited the permanent Titanic exhibit at the Luxor casino in Las Vegas, Nevada, USA. The one large lump of coal on display had the sample number, 94/0036.075: same as the numbers mentioned above, but with 3 more digits after a decimal point. My guess is that 94/0036 is a batch number for all coal retrieved in the 1994 expedition, and that ".075" is a nodule/lump number that is not included on samples offered for sale.)

        Titanic could hold 6611 tons of coal in bunkers and an additional 1092 tons in Hold 3 (Hutchings and de Kerbrech, 2011; full citations at end of this post). There are variable reports on how much coal was onboard at sailing. Sheehan and Sickels-Taves (2002) state just under 6000 tons; website http://atlanticliners.com/white_star_home/titanic_home/ says 5892 tons. Essenhigh (2004) writes that the six bunkers were only half full with 800 tons each (=4800 tons). Smith (2005) cites a website (no longer active) that reported 4427 tons were in the bunkers; Palmer and others (2003) said "more than 4000 metric tons". Steam for the two steam engines and one steam turbine was produced in 29 boilers that contained 159 furnaces. Six hundred tons of coal/day were shoveled into the furnaces around the clock by a total complement of 176 firemen ((Hutchings and de Kerbrech, 2011). There were 73 coal trimmers who handled the coal from loading to maintenance in the bunkers and delivery to the firemen (http://en.wikipedia.org/wiki/Coal_trimmer). One hundred tons of coal ash were disposed at sea each day (Hutchings and de Kerbrech, 2011).  Sheehan and Sickels-Taves (2002) state that the Titanic sank with 2500 tons of coal out of the original load. Coal has been recovered from Titanic ocean bottom debris fields since 1987; coal in various studies and available for sale online is from expeditions in 1994 and 2000.

        Based on testimony of surviving crewmen, there is good evidence for a coal fire in one of the bunkers at the time of sailing. Bunker fires were not uncommon on steamships, caused by spontaneous combustion within the piled coal. The usual solution to quell the fire was to sail at full speed to quickly shovel down the coal pile until the smoldering coal could be removed by simply adding it to the furnaces. However, Titanic survivor reports are not consistent regarding 1) whether the fire started around the time of sailing from Southampton or earlier during sea trials in early April; 2) if the fire was out by Saturday, April 13, or still smoldering at collision; 3) if heat from the fire damaged the adjacent watertight bulkhead; and 4) in what bunker was the fire. Essenhigh (2004), calculating rate of fire spread versus coal pile drawdown, assumed the fire was probably in the top half of the bunker pile, however, Fireman John Dilley testified in 1912 that the fire was at the bottom of the coal pile. There are some, including Essenhigh (2004), who speculate that running full speed through the ice field on April 14 was not to break an Atlantic-crossing speed record but to get rid of the burning bunkered coal, assuming that the fire had not been extinguished the day before. In January 2017, a UK Channel 4 documentary, "Titanic, the New Evidence", proposed that both increased speed and weakening/damage to the hull and bunker bulkhead, due to coal fire heat, were instrumental in the sinking; while the presence of a coal fire, at least after sailing from Southampton, seems undisputed, fatal fire-induced metal damage is still a contentious issue (https://www.smithsonianmag.com/smart-news/coal-fire-may-have-helped-sink-titanic-180961699/ ; https://www.snopes.com/news/2017/01/06/coal-fire-sink-the-titanic/ ).

        I was curious if any analysis of recovered Titanic coal had been undertaken. A 2012 discussion in an online Titanic forum mentions that an analysis of coal recovered in 1994 concluded there were 5 or more geographic coal sources including Pennsylvania anthracite. The "chat" also says that the technical analysis is no longer online (perhaps it is the same as the now-defunct website cited by Smith (2005)). I also could not find any such study that matches those results. However, there are available published scientific studies, using modest-size sample sets, by two groups of researchers. The earliest is by Michael Sheehan and Lauren Sickels-Taves (in 2002 at Eastern Michigan University) from their presentation at a symposium on materials issues in archaeology. The second group of authors (Palmer et al., 2003) presented their findings at both the 2002 Pittsburgh Coal conference and the 2003 TSOP annual meeting in Washington, DC.

        Sheehan and Sickels-Taves, importantly, detail the historic background of coal labor and supply issues in the United Kingdom in spring 1912 that affected the availability and sources of coal loaded on Titanic. From February 22-April 6, 1912, ending just before Titanic's sailing from Southampton, England, on April 10, there was a major UK coal strike that limited the national supply of coal. Some ship sailings were cancelled due to the strike. However, in preparation for the celebrated maiden voyage of Titanic, White Star Line, owner of the ship, scavenged leftover coal in Southampton from other ships of the International Mercantile Marine trust, of which White Star was a member, or had ships already at sea take on extra coal in non-British ports. Sheehan and Sickels-Taves mention that extra coal sacks were even stockpiled in the Second Class public rooms of Titanic's sister ship, Olympic. It is important to note that coal had been already loaded on Titanic at Belfast for the sea trials (Smith, 2005); those coals, I assume, are British since there are few Irish coals and Belfast is close to major British coalfields across the Irish Sea. 

        Sheehan and Sickels-Taves examined 19 coal nodules that were recovered in 2000. They used samples made available to them. They state there was no scientific sampling plan in seafloor recovery, and, therefore, samples may not be representative of the actual range and distribution of coal types onboard. Fifty grams taken from each nodule were used for petrographic, palynological, and trace element analysis (latter data not reported). Testing was done by TES Bretby (formerly Scientific Services Divison of British Coal), UK, and Virginia Polytechnic Institute (VPI), USA.  

        The range of mean vitrinite reflectance for the 19 samples is 0.99% to 2.28% ((British Standard 6127=ISO 7404-5). (See my first blog post in October 2014 for description of 'vitrinite reflectance'.) Fifteen samples are "medium or low volatile bituminous coals with reflectance values between 1.19-1.99%"; eight have reflectances between 1.65 and 1.76%. Only one sample has reflectance greater than 2%, the 2.28%Ro semi-anthracite sample. This range of maturity is consistent with the rank variation within the South Wales Coalfield, which it seems the authors assume is the primary British source of Titanic coal. One other reflectance data point is available for Titanic coal: a medium volatile bituminous 1.15%Ro from the only sample obtained by Smith (2005).

        Three high volatile bituminous coals (0.99-1.09%Ro) of Sheehan and Sickels-Taves were submitted for palynological analysis. Results indicate all are Upper Carboniferous, but stratigraphic location within the British Coal Measures could not be determined. One sample, 7B (0.99%Ro) had a type of spore rare in British coals. The authors also say the rare spore type, not identified, is not common in the eastern USA, but speculate it is still possible the sample could be from an eastern US coal transported to Southampton by the Olympic.

        Palmer and others (2002, 2003) examined 20 samples chosen by the RMS Titanic, Inc. curator because "each piece appeared to be different". Their fixed carbon and volatile matter results indicated an equal distribution of low, medium, and high volatile bituminous coals among the samples. Ash yields are more consistent with British coals than US coals. Trace elements were analyzed by neutron activation, and results were compared to a data base of 24 British coals and 1450 US coals from beds that had been exploited in 1912. Rare earth element data "suggest. . . five distinct sources" (Palmer and others, 2003). Iron, potassium, and arsenic concentration range and median values are more similar to British coals. For most elements, however, the Titanic values were less than both US and UK coals, which the authors suggest is due to differences in the Titanic coal, mined in 1912, versus data base samples collected decades later from the same mine or seam.

        Two of Palmer and others’ samples yielded spores for palynological study. The authors list identified species of the spore assemblages which indicate a Carboniferous Langsettian (Westphalian A) age. They report that nearly all British coalfields contain such beds, but few US coals mined in 1912 were that age.

        One research goal of Palmer and others was to determine the environmental effect of shipwrecked coal in a deep marine setting. In the Titanic samples, higher iodine and bromine than either US or UK coals suggests absorption of those elements from seawater; chlorine data indicates some leaching of that element from the coal. Otherwise the coals are unaltered, and there appears to be “minimal environmental impact” since 1912.

        Both scientific studies conclude most coal samples examined were sourced in Britain. Sheehan and Sickels-Taves write that the limited Titanic sample set shows "considerable uniformity" consistent with usual British sources of coal used by White Star. Although it is known that ships like the Olympic onloaded extra coal from non-British ports during the 1912 strike, it does not appear, with the possible exception of their low-rank sample 7B, that non-typical coals were a significant portion of Titanic fuel. Palmer and others, using two different statistical methods, concluded that 12 samples are probably from the UK, three from US, but provenance of the other four cannot be clearly assigned.

        With results indicating that some of Titanic’s coal may be from the United States, what were the typical US sources of coal for White Star Line ships? The Coal and Coal Trade Journal (vol. 22) wrote in May 23, 1883, that White Star Line renewed a contract with New Central Coal Company of Maryland to fuel their ships in American ports. That company mined Carboniferous low volatile bituminous coal (http://pubs.usgs.gov/sir/2010/5152/pdf/sir2010-5152_fig2.pdf) in the western Maryland Georges Creek basin. I could not find if a contract continued to 1912. Ten years later, the Colliery Engineer (volume 14, August 1893) mentioned a White Star US contract alluding to a Pocahontas coalfield source (West Virginia/Virginia; medium to low volatile bituminous). Gas World (v. 20, March 31, 1894) also mentioned that White Star Line used Pocahontas coal. Gas World continued that Pocahontas was the preferred coal of the US Navy, and some steamships had set Atlantic crossing records using the same. They wrote that Pocahontas coal "is declared by a Newcastle analyst to be 'equal to the best Welsh steam coal, and excellent coal for steam-raising purposes.'" This still leaves questions, however, about the source of high volatile bituminous coals identified by both Sheehan and Sickels-Taves (their possible-US sample 7B) and Palmer and others.

        The results of the scientific studies do call into question colliery source data or coal rank given on some of the Titanic coal COA and labels currently found online. As mentioned earlier, some labels state the rank is anthracite; one COA, without rank assignment, claims that the mine of origin is Six Bells Mine, South Wales Coal Fields, UK (closed since 1988). The study by Sheehan and Sickels-Taves clearly indicates that the exact mine of origin for a particular lump of coal cannot be ascertained with certainty even if the rank is determined. An included table by TES Bretby shows possible early 20th-century South Wales colliery associations for sample reflectance clusters. Most reflectances are correlated with more than one mine, although only the Lake Windsor colliery (Ynysybwl, Wales) is listed for the rank range of the eight 1.65-1.76%Ro samples. In addition, none of the studied coal, recovered in 2000, is, in fact, anthracite, but the limited number of samples does not rule out anthracite onboard. 

        "Titanic: the Artifact Exhibition" at Victoria was one of the itinerant exhibitions of RMS Titanic, Inc.; they have a permanent artifact exhibit now at the Luxor (pyramid-shaped casino) in Las Vegas. Another excellent exhibit of Titanic effects, mostly flotsam, is the permanent one at the Maritime Museum of the Atlantic in Halifax, Nova Scotia (https://maritimemuseum.novascotia.ca/what-see-do/titanic-unsinkable-ship-and-halifax). The flotsam was picked up at sea by both rescue-and-recovery and commercial boats soon after the sinking. Copies of some items were incorporated into James Cameron's 1997 film, Titanic: a stairway newel post ornament like the one shot off the grand staircase, and an entryway entablature panel similar to what Kate Winslet floats on after the ship goes down (the real one is about half the size of the movie version). One hundred fifty victims of the Titanic sinking are buried in Halifax.


     Essenhigh, R.H., 2004, What sank the Titanic? The possible contribution of the bunker fire (abs.): Geological Society of America Abstracts with Program, Vol. 36, No. 5, p. 42.

     Hutchings, D. and de Kerbrech, R., 2011, RMS Titanic Manual: 1909-1912 (Olympic Class): Haynes Owners’ Workshop Manual Series, Zenith Press, 160 pages.

    Palmer, C.A., Finkelman, R.B., Luttrell, G.H., 2002. Coal from aMid-Atlantic Ocean shipwreck: the source of the coal in the Titanic and effects of exposure to seawater. Nineteenth Annual International Pittsburgh Coal Conference, CD-ROM. This citation added July 2020. (Also available at https://www.researchgate.net/publication/291216076_The_source_of_the_coal_on_the_Titanic_and_effects_of_exposure_to_seawater ; this article includes the raw data from the elemental analyses that is only graphed and summarized in the 2003 TSOP abstract.)

     Palmer, C. A., Finkelman, R. B., Luttrell, G. H., Zhang, C., and Eble, C., 2003, The source of the coal in the Titanic and effects of exposure to seawater: Program and Abstracts for the 20th Annual Meeting of The Society for Organic Petrology, v. 20, p. 54-58.

     Sheehan, M.S., and Sickels-Taves, L.B, 2002, The technological analysis of RMS Titanic’s Coal: The enhancement of archaeological research: Material Research Society Symposium Proceedings, vol. 712, p. 525-532 (Materials Issues in Art and Archaeology VI: Symposium held November 26-30, 2001, Boston, Massachusetts, USA).

     Smith, A.H.V., 2005, Coal microscopy in the service of archeology: International Journal of Coal Geology, v. 62, p. 49-59. (http://citeseerx.ist.psu.edu/viewdoc/download?doi=10.1.1.895.8578&rep=rep1&type=pdf)

(This blog post, with very minor changes, appeared earlier as an article in the March 2015 edition of the TSOP newsletter (https://www.tsop.org/newsletters/32_1.pdf)